What happens when you stop sucking on the straw? The
marshmallow is not a solid object. It has many air pockets like
a sponge. By sucking the air out of the jar you decrease the
pressure inside the jar which causes the marshmallow to decrease in
size, becoming a solid. When you release the straw from your
mouth the air rushes back into the marshmallow allowing it to return
to its normal size.
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